Atomic absorption spectrophotometric determination of microamounts of chromium (VI) by using solvent extraction of chromium (III) diethyldithiocarbamate
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Solvent Extraction Of Chromium (VI) From Aqueous
The extraction of chromium (VI) from hydrochloric, hydrobromic, and acetic acid solutions with Tri caprylamine oxide (TCAO) in benzene has been studied. The extractions from hydrochloric and hydrobromic, acid solutions are nearly quantitative and are partial from acetic acid solutions. The optimum conditions for extraction were established from the study of the effect of several variables like–...
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Complexes [CrO2 (C8H5O4) (H2O) 3] and [CrO2 (C8H5O4) (H2O) 3] .H2O were prepared by reduction of CrO3 at room temperature by ethanol in the presence of phthalic acid (H2pht) yield solution that contains monomeric and dimeric Cr (III) complexes. A solution H2pht/Cr molar ratio of 1:1 and 1:2 is indefinitely stable towards precipitation. Their analysis were done by using elemental (C and H), ICP-...
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Supercritical fluid extraction (SFE) provides an environmentally green technique to decontaminate chromium species from solid matrices using supercritical fluid carbon dioxide (ScCO2). Methanol and a small amount of water were found to significantly improve the extraction efficiency. The fluorinated chelating agent lithium bis(trifluoroethyl)-dithiocarbamate (LiFDDC) was effective in removing C...
متن کاملSpectroscopic Determination of Chromium(Vl) during the Reduction of Chromium(VI) to Chromium(III)
Reduction of chromium(VI) to chromium(Ill) by thiourea between pH 3.0 and 5.5 is a key aspect of the chrominm(VI)/thiourea/polyacrylamide gel polymer system used in enhanced oil recovery processes. A method has been developed to determine chromium(Vl) concentration during the reduction of chromium(VI) to chromium(III) in this pH range. The reduction reaction is run in the presence of an acetic ...
متن کاملCatalytic Spectrophotometric Determination of Chromium
chromium(III) up to 100 ng mL−1, and for chromium(VI) up to 200 ng mL−1) were obtained, using the “fixed time” method with detection limits of 4.9 ng mL−1 and 3.8 ng mL−1, respectively. The results suggest that at the reaction conditions chromium(VI) is reduced and chromium(III) is oxidized to an intermediate oxidation state and the catalytic action of chromium is due to the formation of an act...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1972
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.21.26